Researchers demonstrate novel, tunable nanoantennas

“Recently, there has been a lot of interest in fabricating metal-based nanotextured surfaces that are pre-programmed to alter the properties of light in a specific way after incoming light interacts with it,” explained Kimani Toussaint, an associate professor of mechanical science and engineering who led the research.

“For our approach, one can take a nanoarray structure that was already fabricated and further reconfigure the plasmonic, and hence, optical properties of select antennas. Therefore, one can decide after fabrication, rather than before, how they want their nanostructure to modify light.”

The researchers developed a novel, metal, pillar-bowtie nanoantenna (p-BNA)  array template on 500-nanometer tall glass pillars (or posts). In doing so, they demonstrated that the gap size for either individual or multiple p-BNAs can be tuned down to approximately 5 nm (approx. 4x smaller than what is currently achievable using conventional electron-beam lithography techniques).

“On a fundamental level, our work demonstrates electron-beam based manipulation of nanoparticles an order of magnitude larger than previously possible, using a simple SEM operating at only a fraction of the electron energies of previous work,” said Brian Roxworthy, who earned his PhD in electrical and computer engineering (ECE) at Illinois and was first author of the paper published in Nature Communications.

“The dramatic deformation of the nanoantennas we observe is facilitated by strong in-gap plasmonic modes excited by the passing electrons, which give rise to nanoNewton-magnitude gradient forces on the constituent metal particles.”

The interdisiciplinary research team–that included Abdul Bhuiya (MS student in ECE student), Xin Yu (ECE post-grad), and K.C. Chow (a research engineer at the Micro and Nanotechnology Laboratory)—also demonstrated that a standard scanning electron microscope (SEM) can be used to deform either individual p-BNA structures or groups of p-BNAs within a sub-array with velocities as large as 60 nanometers per second. A photonic-crystal fiber was used to generate (quasi-white light) supercontinuum to probe the spectral response of select regions within the array.

The researchers said the importance of this work is three-fold: It enables tuning of the optical (plasmonic) response of the nanoantennas, down to the level of a single nanoantenna (approximately 250 nanometers across); it could lead to unique, spatially addressable nanophotonic devices for sensing and particle manipulation, for example; and, it provides a fertile platform for studying mechanical, electromagnetic, and thermal phenomena in a nanoscale system.
 
The team believes that the relatively high aspect ratio (pillar height-to-thickness) of 4.2 for the p-BNAs, along with a significant thermal contribution, permit sufficient compliance of the pillars to be actuated by electron-beam-induced gradient forces.

“Our fabrication process shows for the first time an innovative way of fabricating plasmonic nanoantenna structures under the SEM, which avoids complications such as proximity effects from conventional lithography techniques,” Bhuiya said. “This process also reduces the gap of the nanoantennas down to ~5 nm under SEM with a controlled reduction rate. With this new fabrication technique, it opens an avenue to study different phenomena which leads to new exciting research fields.”