Laser pulse creates exotic order in quantum material

The studied layered crystal, grown by Kai Rossnagel’s team in Kiel, is characterized by a minimal distortion of the crystal structure at room temperature. This is due to the special structure of the crystal, in which thin layers of metal and sulfur atoms are stacked on top of each other and only weakly bound. If these layers are now bombarded with ultrashort laser flashes, the distortion changes its orientation within a trillionth of a second, abruptly increasing the electrical conductivity of the material. Although both types of distortions have an ordered structure and associated crystalline properties, a highly disordered state can be observed during the transition.

“After exciting the material with light, the atoms in the crystal structure have yet to find their new, slightly different positions. This transforms the material into an unusually disordered, so-called hexatic state,” says Till Domröse, PhD student at MPI and first author of the study now published in the journal Nature Materials. “This state is otherwise mainly observed in liquid crystals. In our experiments, however, it is extremely volatile and has already disappeared after the fractions of a nanosecond.” Making the hexatic state visible placed high demands on the measurement technology used. On the one hand, for example, a very fast temporal resolution is required to take a sufficiently short snapshot. On the other hand, the structural changes in the material are so subtle that they can only be seen with a very high sensitivity to atomic positions. Electron microscopes in principle provide the necessary spatial resolution, but are typically not fast enough.

In recent years, the Göttingen team led by Max Planck Director Claus Ropers has closed this gap by developing an “ultrafast” electron microscope capable of imaging even unimaginably rapid processes in the nanocosmos. “This microscope was also used in these experiments and enabled us to capture the unusually ordered phase and its temporal evolution in a series of images,” Ropers explains. “At the same time, we developed a new high-resolution diffraction mode that will be essential for studying many other functional nanostructures.”

The project was carried out with support from CRC 1073, “Atomic scale control of energy conversion.”