Parallel planar heterojunction strategy for efficient solar cells

Recently, a team led by Prof. WANG Mingtai from the Institute of Solid State Physics, Hefei Institutes of Physical Science (HFIPS), Chinese Academy of Sciences (CAS) has put forward an intriguing approach to enhance the efficiency of solar cells. Their focus on the potential antimony trisulfide (Sb₂S₃) as a photovoltaic absorber has led to a Parallel Planar Heterojunction (PPHJ) strategy for the preparation of highly efficient solar cells.

Their findings have been published in Angewandte Chemie International Edition.

One of the current challenges in the terrestrial utility of photovoltaic electricity is the absence of low-cost, efficient, and stable materials as well as the related photovoltaic devices for converting photons to electrons. Typically, two independent planar heterojunction (PHJ) subcells are stacked in tandem to create efficient solar cells. However, the need for an interfacial layer for the recombination of opposite charges from the top and bottom subcells increases complexity to material selection and device preparation.

“This is why we introduced the PPHJ strategy in our research.” Prof. CHEN Chong explains, “it enables us to tap into the practical potential of creating efficient multiple PHJ solar cells.”

The Sb₂S₃-based PPHJ device consists of two types of conventional PHJ subcells connected in parallel. Researchers explained the divided tasks. The Sb₂S₃-based PHJ subcells are responsible for absorption and charge generation, while the CH₃NH₃PbI₃-based PHJ subcells govern the electron transport towards collection electrode. Despite the two types of subcells, the PPHJ device remains an Sb₂S₃ device in nature.

The outcome is a remarkable increase in the efficiency of solution-processed Sb₂S₃ solar cells, achieving an impressive 8.32% efficiency, the highest among all Sb₂S₃ devices.

“Indeed, our strategy simplifies the preparation process by allowing for the conventional sequential depositions of multiple PHJ layers,” said CHEN, “It eliminates the typical complexity associated with both tandem and parallel tandem PHJ systems.”

“This study paves the way for the conceptual design of low-cost and efficient partially or fully inorganic solar cells, thus promoting their development,” added CHEN.

Journal: Angewandte Chemie International Edition
DOI: 10.1002/anie.202312951
Article Title: Parallel Planar Heterojunction Strategy Enables Sb2S3 Solar Cells with Efficiency Exceeding 8%
Article Publication Date: 31-Oct-2023

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