A solution for cleaning up PFAS, one of the world's most intractable pollutants

A cluster of industrial chemicals known by the shorthand term “PFAS” has infiltrated the far reaches of our planet with significance that scientists are only beginning to understand.

PFAS – Per- and polyfluoroalkyl substances – are human-made fluorine compounds that have given us nonstick coatings, polishes, waxes, cleaning products and firefighting foams used at airports and military bases.

They are in consumer goods like carpets, wall paint, popcorn bags and water-repellant shoes, and they are essential in the aerospace, automotive, telecommunications, data storage, electronic and healthcare industries.

The carbon-fluorine chemical bond, among nature's strongest, is the reason behind the wild success of these chemicals, as well as the immense environmental challenges they have caused since the 1940s.

PFAS residues have been found in some of the most pristine water sources, and in the tissue of polar bears. Science and industry are called upon to clean up these persistent chemicals, a few of which, in certain quantities, have been linked to adverse health effects for humans and animals.

Among those solving this enormously difficult problem are engineers in the Walter Scott, Jr. College of Engineering at Colorado State University. CSU is one of a limited number of institutions with the expertise and sophisticated instrumentation to study PFAS by teasing out their presence in unimaginably trace amounts.

Now, CSU engineers led by Jens Blotevogel, research assistant professor in the Department of Civil and Environmental Engineering, have published a new set of experiments tackling a particular PFAS compound called hexafluoropropylene oxide dimer acid, better known by its trade name, GenX.

The chemical, and other polymerization processes that use similar chemistries, have been in use for about a decade. They were developed as a replacement for legacy PFAS chemicals known as “C8” compounds that were – and still are – particularly persistent in water and soil, and very difficult to clean up (hence their nickname, “forever chemicals”).

GenX has become a household name in the Cape Fear basin area of North Carolina, where it was discovered in the local drinking water a few years ago.

The responsible company, Chemours, has committed to reducing fluorinated organic chemicals in local air emissions by 99.99%, and air and water emissions from its global operations by at least 99% by 2030. For the last several years, Chemours has also funded Blotevogel's team at CSU as they test innovative methods that would help the environment as well as assist the company's legacy cleanup obligations.

Writing in Environmental Science and Technology, Blotevogel teamed up with Tiezheng Tong, assistant professor in civil and environmental engineering, to demonstrate an effective “treatment train” that combines multiple technologies to precisely isolate and destroy GenX residues in water.

One of the current practices for treating GenX-contaminated water is high-temperature incineration – a process that is “excessively expensive,” according to the researchers, and very wasteful for water and energy recovery. “It works,” Blotevogel said, “but it's not sustainable.”

The researchers are offering a better solution. Tong, a leading expert in membrane filtration and desalination methods for environmental hazards, employed a nanofiltration membrane with appropriate pore sizes to filter out 99.5% of dissolved GenX compounds. Once that concentrated waste stream is generated, the researchers showed that electrochemical oxidation, which Blotevogel considers one of the most viable technologies for destructive PFAS cleanup, can then break down the waste into harmless products.

Currently, companies can also use several measures for removal of PFAS from water to acceptable levels: adsorption to activated carbon, ion exchange, and reverse osmosis. While all three of these technologies can be highly effective, they do not result directly in destruction of PFAS compounds, Blotevogel said.

The CSU researchers alternative solution of electrochemical treatment uses electrodes to chemically change the PFAS into more benign compounds. Blotevogel's lab has demonstrated several successful pilot-scale decontamination efforts, and is working to continue optimizing their methodologies. Combined with Tong's nanofiltration system, the waste stream would be directed and concentrated, saving companies money and lowering the entire process's carbon footprint.

The researchers hope to continue working together to refine their process, for example, by testing different types of filtration membranes to determine the most optimal materials and design.

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Link to paper: https://pubs.acs.org/doi/abs/10.1021/acs.est.9b03171